Adhesive

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For a general and scholarly article about Adhesives see Wikipedia: http://en.wikipedia.org/wiki/Adhesives

Adhesives By Purpose

Wood

  • PVA
  • Animal
  • Resin
  • Polyurethane
  • Acrylic
  • Epoxy

see Wood glues

Metal

  • Epoxy
  • Polyurethane
  • Contact

Plastics - PVC, ABS

  • Solvent glues
  • Solvents
  • Household gloss paint will glue pvc, but is less strong than a solvent welded joint

Plastics - hard

  • Epoxy
  • Polyurethane
  • ...

Plastics - polyethylene, nylon

  • No glue can stick these directly
  • Flamed polythene and nylon can be glued
  • Melting the surfaces together also works, if both materials being joined are the same substance. Local heating can be achieved on flared circular joints by spinning while applying pressure.

Fabric

  • Latex, eg Copydex

Paper & Card

  • PVA
  • Gum
  • Glue sticks (eg Pritt-stick) (PVA or PVP)
  • Spray-type photo fixing etc
  • Wallpaper paste
  • Starch

Oil lines

  • Red hermetite

Plaster

to consolidate & stabilise loose plaster:

  • dilute PVA
  • limewash

Adhesives By Type

Cyanoacrylate

  • aka superglue, crazy glue
  • CA (cyanoacrylate) is famous for accidentally gluing skin together
  • debonders available to unstick skin,
  • cyanoacrylacte activators are available to speed up setting to 2 or 3 seconds, but these reduce final strength.
  • For non-porous surfaces.
  • Its low shear strength enables it to be used as a removable glue in some cases, eg for mounting items to a block on a lathe.
  • can be used as a thread lock
  • Cyanoacrylates are used to glue human and animal tissue after accidents. The medical grade is a slightly different formula with improved medical properties, but standard superglue also works and was previously used medically.
  • CA is also effective at stoping bleeding at trauma sites.
  • When added to baking soda (Sodium bicarbonate) Cyanoacrylate glue forms a hard, lightweight filler/adhesive (baking soda is first used to fill a gap then the adhesive is dripped into the baking soda). This works well with porous materials that the glue doesn't work well with alone.
  • Thin CA is occasionally used as a tough glossy wood varnish for small items such as turned pens.
  • Moisture triggers setting
  • Opened bottles keep longer if stored in a container with a desiccant (eg silica gel)
  • Cured CA can be removed with acetone or methylene chloride.
  • A few hours in the freezer can make it brittle
  • Accidetal gluing of eyes is a real risk with CA
  • Very low flash point

Epoxy Resin

  • Araldite is a well known epoxy resin formulation
  • 2 part resin
  • Available as liquid resin tubes, putty sticks, or in standard 380ml building cartridges with self mixing nozzles.
  • Epoxies come mixed with many different fillers and modifiers, giving them a range of properties
  • Tough
  • Good chemical resistance.
  • Car accessory shops sell tougher epoxies than Araldite.
  • The quick setting types are much weaker
  • Vulnerable to UV, which causes degradation.
  • Heating the mix (in tinfoil on a low ring, or over boiling water) until runny makes it set very much faster. Don't overheat it.
  • Some types are heat resistant, some not. The ones that aren't may claim they are on the basis that they survive heat, even if they do lose all strength when hot.
  • Heat while setting makes it more heat and chemical resistance once set.
  • More strength and cost than polyester or vinylester resins.
  • Epoxies are used as powder coatings (a tough paint-like finish)
  • Electrically insulating, but metal loaded epoxies can be conductive
  • Suitable for work where failure could cause injury, eg chairs, fixing heavy loads to walls, structural repairs to wood & masonry, etc.
  • Suitable for wood, metal, glass, stone, and some plastics.
  • Vinegar will clean up uncured and semi-cured epoxy, but not once cured.
  • 1:1 resin to hardener ratio typical, but ratios of upto 5:1 are also available.

See also:

hot-melt glue

  • Almost instant setting
  • Handy for creating structures where glue needs to set at each stage before the next can be glued
  • not a strong or durable glue
  • Most common hot melt glue stick chemistry is amorphous polypropylene plus tackifiers and fillers. Several other chemistries also exist.
  • Polyethylene requires temperatures above those of standard retail glue guns to work, if you put polythene in an ordinary glue gun it will just soften enough to block it.
  • Low melting point glues and guns are also available. Often used by kids due to nearly instant setting.

Pdf hot melt glue datasheets

PVA

PVA has a wide range of uses in building and DIY.

  • There are White and yellow types of PVA
  • A good general purpose wood glue
  • Reduces permeability of cement mortar & increases adhesion
  • Use as a plaster size
  • softens when wet
  • Exterior grade PVAs available, but are not waterproof
  • Not suitable for woodwork where failure could cause injury, eg chairs, beds ets.

Acrylic mastic type

(e.g. "solvent-free Gripfill/No-more-nails/etc")

Caulk

  • Caulk is a low cost flexible acrylic formula used for filling
  • Paintable

Solvent based building adhesives

(Gripfill etc)

? type

"Sticks like SH!T" etc

Polyurethane

Polyester resin

  • tough
  • sticks a wide range of materials
  • used in fibreglass work
  • used to fill damaged exterior woodwork, eg sash windows
  • available in clear or colours
  • car body filler is polyester resin
  • All resin glues contain various fillers to reduce cost and modify their properties.
  • 10:1 resin to hardener ratio is typical
  • ideal for filling rusted metal windows

See also:

Vinylester Resin

Silicone

  • Silicone Sealant is a satisfactory glue in shear, but has little strength in tension.
  • Silicone is used to glue glass aquaria together, but this is a tougher formula than builders' silicone sealant.
  • Building silicones are RTV, room temperature vulcanised.
  • There are several types of silicone
  • For more information see Silicone Sealant

Solvent cements

Solvent based cements are plastics dissolved in a solvent. These cements, and solvents alone, are used to glue soluble plastics.

Tile adhesives

  • Most are modified cement formulae
  • Ready mixed types contain a set preventer that evaporates on use.
  • See BAL Adhesives guide for information on different types

Wallpaper Paste

how long will it store once mixed?

Starch

  • Glue for wallpaper, card & paper.
  • To make starch glue, boil some starch (eg flour, oats, etc) until it changes from white to semi-clear. Add a little alum to prevent mould if you're not using it immediately.
  • To make a starch gluestick, parboil a potato. Suitable for gluing paper, just wipe with the potato and press together. Will not store.
  • Low cost, complete safety and easy to wash out; ideal for kids

Adhesive Selector Grid

Which adhesive is best for any 2 given materials?

http://www.elessar.org.uk/adhesives.pdf

http://www.thistothat.com/


Structural Adhesives

Structural adhesives or engineering adhesives are used where failure could cause injury or other undesired consequences. These high strength & higher reliability adhesives include:

  • epoxies
  • polyurethane
  • acrylic
  • cyanoacrylate

Preparation

In the great majority of cases, to obtain a good bond surfaces should be prepared so they are:

  • clean
  • dry
  • loose or flaky material removed
  • degreased

Roughening smooth surfaces increases the adhesive bond strength, and in many cases is necessary to obtain sufficient strength.

Moulding tools

Sometimes adhesives need to be moulded.

Fugee & Fugenboy

PTFE

Polythene

Fillers

Fillers are low cost dry powders present in a lot of adhesives. They reduce cost and in some cases can improve strength. They also affect the adhesive properties to some extent.

Additional fillers can be mixed into adhesives to reduce cost further. Each type of filler will have effects on the glue formulation. Adding fillers does reduce final strength in most cases, but fibrous fillers can sometimes increase it.

Dry powders such as talc and iron oxide are often used to extend adhesives, but weaken the final result.

Sand is very tough, and can be mixed into resins, which bond to it well. This reduces cost, but the resulting mix is not sandable.

Sawdust consists of lots of short fibres, and thus can act as reinforcement as well as a bulk filler. It is less hard than most glues, but will strengthen some.

Fillers should not be added to adhesive sand compounds such as Geotex, which is used to fill gaps in block paving work, as this generally results in failure. Such products aren't cheap and are already thinned as far as they can be. The addition of sand is a common cause of failure.

Suppliers

See Also

PVA

Book: 'On boat construction' by Gougeon Brothers is an expert guide to use of epoxies.

BAL Adhesives tables

Glue Terminology

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